------------------------------------------------------------------------------ MSDS for PHENYLHYDRAZINE Page 1 ------------------------------------------------------------------------------ ------------------------------------------------------------------------------ 1 - PRODUCT IDENTIFICATION ------------------------------------------------------------------------------ PRODUCT NAME: PHENYLHYDRAZINE FORMULA: C6H5NHNH2 FORMULA WT: 108.14 CAS NO.: 00100-63-0 NIOSH/RTECS NO.: MV8925000 COMMON SYNONYMS: HYDRAZINOBENZENE PRODUCT CODES: T737 EFFECTIVE: 10/24/86 REVISION #02 PRECAUTIONARY LABELLING BAKER SAF-T-DATA(TM) SYSTEM HEALTH - 3 SEVERE (CANCER CAUSING) FLAMMABILITY - 2 MODERATE REACTIVITY - 1 SLIGHT CONTACT - 3 SEVERE (LIFE) HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD). LABORATORY PROTECTIVE EQUIPMENT GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES; CLASS B EXTINGUISHER PRECAUTIONARY LABEL STATEMENTS WARNING COMBUSTIBLE HARMFUL IF SWALLOWED CAUSES SEVERE IRRITATION EXCEPTIONAL CONTACT HAZARD - READ MATERIAL SAFETY DATA SHEET KEEP AWAY FROM HEAT, SPARKS, FLAME. DO NOT GET IN EYES, ON SKIN, ON CLOTHING. AVOID BREATHING VAPOR. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. IN CASE OF FIRE, USE ALCOHOL FOAM, DRY CHEMICAL, CARBON DIOXIDE - WATER MAY BE INEFFECTIVE. FLUSH SPILL AREA WITH WATER SPRAY. SAF-T-DATA(TM) STORAGE COLOR CODE: RED STRIPE (STORE SEPARATELY) ------------------------------------------------------------------------------ 2 - HAZARDOUS COMPONENTS ------------------------------------------------------------------------------ COMPONENT % CAS NO. PHENYLHYDRAZINE 90-100 100-63-0 ------------------------------------------------------------------------------ 3 - PHYSICAL DATA ------------------------------------------------------------------------------ ------------------------------------------------------------------------------ MSDS for PHENYLHYDRAZINE Page 2 ------------------------------------------------------------------------------ BOILING POINT: 243 C ( 469 F) VAPOR PRESSURE(MM HG): N/A MELTING POINT: 19 C ( 66 F) VAPOR DENSITY(AIR=1): 3.7 SPECIFIC GRAVITY: 1.10 EVAPORATION RATE: N/A (H2O=1) (BUTYL ACETATE=1) SOLUBILITY(H2O): SLIGHT (0.1 TO 1 %) % VOLATILES BY VOLUME: 100 APPEARANCE & ODOR: COLORLESS TO PALE YELLOW LIQUID WITH WEAK AROMATIC ODOR. ------------------------------------------------------------------------------ 4 - FIRE AND EXPLOSION HAZARD DATA ------------------------------------------------------------------------------ FLASH POINT (CLOSED CUP 89 C ( 192 F) NFPA 704M RATING: 3-2-0 FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A % FIRE EXTINGUISHING MEDIA USE ALCOHOL FOAM, DRY CHEMICAL OR CARBON DIOXIDE. (WATER MAY BE INEFFECTIVE.) SPECIAL FIRE-FIGHTING PROCEDURES FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE. MOVE CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK. USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL. UNUSUAL FIRE & EXPLOSION HAZARDS CONTACT WITH STRONG OXIDIZERS MAY CAUSE FIRE OR EXPLOSION. GIVES OFF FLAMMABLE VAPORS. VAPORS MAY FORM EXPLOSIVE MIXTURE WITH AIR. CLOSED CONTAINERS EXPOSED TO HEAT MAY EXPLODE. TOXIC GASES PRODUCED NITROGEN OXIDES, CARBON MONOXIDE, CARBON DIOXIDE ------------------------------------------------------------------------------ 5 - HEALTH HAZARD DATA ------------------------------------------------------------------------------ ACGIH DENOTES THAT THIS SUBSTANCE IS SUSPECT OF CARCINOGENIC POTENTIAL FOR MAN. THRESHOLD LIMIT VALUE (TLV/TWA): 20 MG/M3 ( 5 PPM) SHORT-TERM EXPOSURE LIMIT (STEL): 45 MG/M3 ( 10 PPM) PERMISSIBLE EXPOSURE LIMIT (PEL): 22 MG/M3 ( 5 PPM) TOXICITY: LD50 (ORAL-RABBIT)(MG/KG) - 80 LD50 (ORAL-RAT)(MG/KG) - 188 LD50 (ORAL-GUINEA PIG) (MG/KG) - 80 CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO ------------------------------------------------------------------------------ MSDS for PHENYLHYDRAZINE Page 3 ------------------------------------------------------------------------------ EFFECTS OF OVEREXPOSURE VAPORS MAY BE IRRITATING TO SKIN, EYES, AND MUCOUS MEMBRANES. CONTACT WITH SKIN OR EYES MAY CAUSE SEVERE IRRITATION OR BURNS. PROLONGED CONTACT MAY CAUSE SKIN SENSITIZATION. INGESTION MAY CAUSE NAUSEA AND VOMITING. CHRONIC EFFECTS OF OVEREXPOSURE MAY INCLUDE KIDNEY AND/OR LIVER DAMAGE. TARGET ORGANS BLOOD, RESPIRATORY SYSTEM, SKIN, LIVER, KIDNEYS MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE NONE IDENTIFIED ROUTES OF ENTRY INHALATION, INGESTION, SKIN CONTACT, EYE CONTACT EMERGENCY AND FIRST AID PROCEDURES CALL A PHYSICIAN. IF SWALLOWED, DO NOT INDUCE VOMITING; IF CONSCIOUS, GIVE LARGE AMOUNTS OF WATER. IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. TLV AND PEL LISTED DENOTE (SKIN). ------------------------------------------------------------------------------ 6 - REACTIVITY DATA ------------------------------------------------------------------------------ STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR CONDITIONS TO AVOID: HEAT, FLAME, OTHER SOURCES OF IGNITION, AIR, LIGHT, SUNLIGHT INCOMPATIBLES: STRONG OXIDIZING AGENTS, METAL OXIDES DECOMPOSITION PRODUCTS: OXIDES OF NITROGEN, CARBON MONOXIDE, CARBON DIOXIDE ------------------------------------------------------------------------------ 7 - SPILL AND DISPOSAL PROCEDURES ------------------------------------------------------------------------------ STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING. SHUT OFF IGNITION SOURCES; NO FLARES, SMOKING OR FLAMES IN AREA. STOP LEAK IF YOU CAN DO SO WITHOUT RISK. USE WATER SPRAY TO REDUCE VAPORS. TAKE UP WITH SAND OR OTHER NON-COMBUSTIBLE ABSORBENT MATERIAL AND PLACE INTO CONTAINER FOR LATER DISPOSAL. FLUSH AREA WITH WATER. DISPOSAL PROCEDURE DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL ENVIRONMENTAL REGULATIONS. EPA HAZARDOUS WASTE NUMBER: D002 (CORROSIVE WASTE) ------------------------------------------------------------------------------ 8 - PROTECTIVE EQUIPMENT ------------------------------------------------------------------------------ ------------------------------------------------------------------------------ MSDS for PHENYLHYDRAZINE Page 4 ------------------------------------------------------------------------------ VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV REQUIREMENTS. RESPIRATORY PROTECTION: RESPIRATORY PROTECTION REQUIRED IF AIRBORNE CONCENTRATION EXCEEDS TLV. AT CONCENTRATIONS ABOVE 5 PPM, A SELF-CONTAINED BREATHING APPARATUS IS ADVISED. EYE/SKIN PROTECTION: SAFETY GOGGLES AND FACE SHIELD, UNIFORM, PROTECTIVE SUIT, BUTYL RUBBER GLOVES ARE RECOMMENDED. ------------------------------------------------------------------------------ 9 - STORAGE AND HANDLING PRECAUTIONS ------------------------------------------------------------------------------ SAF-T-DATA(TM) STORAGE COLOR CODE: RED STRIPE (STORE SEPARATELY) SPECIAL PRECAUTIONS KEEP CONTAINER TIGHTLY CLOSED. STORE IN COOL, DRY, WELL-VENTILATED AREA AWAY FROM HEAT, SPARKS, OR FLAME. STORE IN LIGHT-RESISTANT CONTAINERS. PRODUCT MAY SOLIDIFY AT ROOM TEMPERATURE. ------------------------------------------------------------------------------ 10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION ------------------------------------------------------------------------------ DOMESTIC (D.O.T.) PROPER SHIPPING NAME CORROSIVE LIQUID, N.O.S. (PHENYLHYDRAZINE) HAZARD CLASS CORROSIVE MATERIAL (LIQUID) UN/NA UN1760 LABELS POISON INTERNATIONAL (I.M.O.) PROPER SHIPPING NAME PHENYLHYDRAZINE HAZARD CLASS 6.1 UN/NA UN2572 LABELS POISON