------------------------------------------------------------------------------ MSDS for TITANIUM TRICHLORIDE, (20% SOLUTION) Page 1 ------------------------------------------------------------------------------ ------------------------------------------------------------------------------ 1 - PRODUCT IDENTIFICATION ------------------------------------------------------------------------------ PRODUCT NAME: TITANIUM TRICHLORIDE, (20% SOLUTION) FORMULA: TICL3 FORMULA WT: 154.26 CAS NO.: 07705-07-9 NIOSH/RTECS NO.: XR1924000 COMMON SYNONYMS: TITANIUM(III)CHLORIDE SOLUTION; TITANOUS CHLORIDE SOLUTION PRODUCT CODES: V884 EFFECTIVE: 03/18/87 REVISION #02 PRECAUTIONARY LABELLING BAKER SAF-T-DATA(TM) SYSTEM HEALTH - 3 SEVERE (POISON) FLAMMABILITY - 0 NONE REACTIVITY - 2 MODERATE CONTACT - 3 SEVERE (CORROSIVE) HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD). LABORATORY PROTECTIVE EQUIPMENT GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES PRECAUTIONARY LABEL STATEMENTS DANGER CAUSES BURNS HARMFUL IF SWALLOWED OR INHALED DO NOT GET IN EYES, ON SKIN, ON CLOTHING. DO NOT BREATHE VAPOR. KEEP IN TIGHTLY CLOSED CONTAINER IN A COOL AREA. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. IN CASE OF SPILL, FLUSH AWAY BY FLOODING WITH WATER APPLIED QUICKLY TO ENTIRE SPILL. NEUTRALIZE WASHINGS WITH LIME OR SODA ASH. SAF-T-DATA(TM) STORAGE COLOR CODE: WHITE (CORROSIVE) ------------------------------------------------------------------------------ 2 - HAZARDOUS COMPONENTS ------------------------------------------------------------------------------ COMPONENT % CAS NO. TITANIUM TRICHLORIDE, (20% SOLUTION) 15-25 7705-07-9 HYDROCHLORIC ACID 1-4 7647-01-0 PHOSPHORIC ACID 2-4 7664-38-2 ------------------------------------------------------------------------------ 3 - PHYSICAL DATA ------------------------------------------------------------------------------ BOILING POINT: N/A VAPOR PRESSURE(MM HG): N/A ------------------------------------------------------------------------------ MSDS for TITANIUM TRICHLORIDE, (20% SOLUTION) Page 2 ------------------------------------------------------------------------------ MELTING POINT: N/A VAPOR DENSITY(AIR=1): N/A SPECIFIC GRAVITY: 1.22 EVAPORATION RATE: N/A (H2O=1) (BUTYL ACETATE=1) SOLUBILITY(H2O): COMPLETE (IN ALL PROPORTIONS) % VOLATILES BY VOLUME: 80 APPEARANCE & ODOR: REDDISH-VIOLET SOLUTION WITH SLIGHT ODOR OF HCL. ------------------------------------------------------------------------------ 4 - FIRE AND EXPLOSION HAZARD DATA ------------------------------------------------------------------------------ FLASH POINT (CLOSED CUP N/A FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A % FIRE EXTINGUISHING MEDIA USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE. SPECIAL FIRE-FIGHTING PROCEDURES FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE. TOXIC GASES PRODUCED HYDROGEN CHLORIDE, PHOSPHORUS OXIDE ------------------------------------------------------------------------------ 5 - HEALTH HAZARD DATA ------------------------------------------------------------------------------ CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO EFFECTS OF OVEREXPOSURE INHALATION OF VAPORS MAY CAUSE SEVERE IRRITATION OF THE RESPIRATORY SYSTEM. LIQUID MAY CAUSE BURNS TO SKIN AND EYES. INGESTION MAY CAUSE IRRITATION AND BURNING TO MOUTH AND STOMACH. TARGET ORGANS NONE IDENTIFIED MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE NONE IDENTIFIED ROUTES OF ENTRY INHALATION, INGESTION, SKIN CONTACT, EYE CONTACT EMERGENCY AND FIRST AID PROCEDURES CALL A PHYSICIAN. IF SWALLOWED, DO NOT INDUCE VOMITING; IF CONSCIOUS, GIVE WATER, MILK, OR MILK OF MAGNESIA. IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. ------------------------------------------------------------------------------ MSDS for TITANIUM TRICHLORIDE, (20% SOLUTION) Page 3 ------------------------------------------------------------------------------ WASH CLOTHING BEFORE RE-USE. ------------------------------------------------------------------------------ 6 - REACTIVITY DATA ------------------------------------------------------------------------------ STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR CONDITIONS TO AVOID: HEAT INCOMPATIBLES: STRONG OXIDIZING AGENTS, STRONG BASES, AMINES, ORGANIC MATERIALS, COMBUSTIBLE MATERIALS DECOMPOSITION PRODUCTS: HYDROGEN CHLORIDE, OXIDES OF PHOSPHORUS ------------------------------------------------------------------------------ 7 - SPILL AND DISPOSAL PROCEDURES ------------------------------------------------------------------------------ STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING. STOP LEAK IF YOU CAN DO SO WITHOUT RISK. VENTILATE AREA. NEUTRALIZE SPILL WITH SODA ASH OR LIME. WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND COVER; REMOVE FROM AREA. FLUSH SPILL AREA WITH WATER. J. T. BAKER NEUTRASORB(R) OR NEUTRASOL(R) "LOW NA+" ACID NEUTRALIZERS ARE RECOMMENDED FOR SPILLS OF THIS PRODUCT. DISPOSAL PROCEDURE DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL ENVIRONMENTAL REGULATIONS. EPA HAZARDOUS WASTE NUMBER: D002 (CORROSIVE WASTE) ------------------------------------------------------------------------------ 8 - PROTECTIVE EQUIPMENT ------------------------------------------------------------------------------ VENTILATION: USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP VAPOR AND MIST LEVELS AS LOW AS POSSIBLE. RESPIRATORY PROTECTION: NONE REQUIRED WHERE ADEQUATE VENTILATION CONDITIONS EXIST. IF AIRBORNE CONCENTRATION IS HIGH, A CHEMICAL CARTRIDGE RESPIRATOR WITH ACID CARTRIDGE IS RECOMMENDED. IF CONCENTRATION EXCEEDS CAPACITY OF CARTRIDGE RESPIRATOR, A SELF- CONTAINED BREATHING APPARATUS IS ADVISED. EYE/SKIN PROTECTION: SAFETY GOGGLES AND FACE SHIELD, UNIFORM, PROTECTIVE SUIT, ACID-RESISTANT GLOVES ARE RECOMMENDED. ------------------------------------------------------------------------------ 9 - STORAGE AND HANDLING PRECAUTIONS ------------------------------------------------------------------------------ SAF-T-DATA(TM) STORAGE COLOR CODE: WHITE (CORROSIVE) ------------------------------------------------------------------------------ MSDS for TITANIUM TRICHLORIDE, (20% SOLUTION) Page 4 ------------------------------------------------------------------------------ SPECIAL PRECAUTIONS KEEP CONTAINER TIGHTLY CLOSED. STORE IN CORROSION-PROOF AREA. ------------------------------------------------------------------------------ 10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION ------------------------------------------------------------------------------ DOMESTIC (D.O.T.) PROPER SHIPPING NAME CORROSIVE LIQUID, N.O.S. (TITANIUM TRICHLORIDE, (20% HAZARD CLASS CORROSIVE MATERIAL (LIQUID) UN/NA UN1760 LABELS CORROSIVE INTERNATIONAL (I.M.O.) PROPER SHIPPING NAME TITANIUM TRICHLORIDE, MIXTURE, NONPYROPHORIC HAZARD CLASS 8 UN/NA UN2869 LABELS CORROSIVE