------------------------------------------------------------------------------ MSDS for AMMONIUM FLUORIDE, 40% SOLUTION Page 1 ------------------------------------------------------------------------------ ------------------------------------------------------------------------------ 1 - PRODUCT IDENTIFICATION ------------------------------------------------------------------------------ PRODUCT NAME: AMMONIUM FLUORIDE, 40% SOLUTION FORMULA: NH4F FORMULA WT: 37.04 CAS NO.: 12125-01-8 PRODUCT CODES: 0704,5357,0705,0702 EFFECTIVE: 12/10/86 REVISION #03 PRECAUTIONARY LABELLING BAKER SAF-T-DATA(TM) SYSTEM HEALTH - 3 SEVERE (POISON) FLAMMABILITY - 0 NONE REACTIVITY - 1 SLIGHT CONTACT - 2 MODERATE HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD). LABORATORY PROTECTIVE EQUIPMENT GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES PRECAUTIONARY LABEL STATEMENTS WARNING CAUSES SEVERE IRRITATION MAY BE FATAL IF SWALLOWED EXCEPTIONAL CONTACT HAZARD - READ MATERIAL SAFETY DATA SHEET DO NOT GET IN EYES, ON SKIN, ON CLOTHING. AVOID BREATHING VAPOR. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. SAF-T-DATA(TM) STORAGE COLOR CODE: BLUE (HEALTH) ------------------------------------------------------------------------------ 2 - HAZARDOUS COMPONENTS ------------------------------------------------------------------------------ COMPONENT % CAS NO. AMMONIUM FLUORIDE 40 12125-01-8 ------------------------------------------------------------------------------ 3 - PHYSICAL DATA ------------------------------------------------------------------------------ BOILING POINT: N/A VAPOR PRESSURE(MM HG): N/A MELTING POINT: N/A VAPOR DENSITY(AIR=1): N/A SPECIFIC GRAVITY: 1.02 EVAPORATION RATE: N/A (H2O=1) (BUTYL ACETATE=1) ------------------------------------------------------------------------------ MSDS for AMMONIUM FLUORIDE, 40% SOLUTION Page 2 ------------------------------------------------------------------------------ SOLUBILITY(H2O): COMPLETE (IN ALL PROPORTIONS) % VOLATILES BY VOLUME: 60 APPEARANCE & ODOR: CLEAR, COLORLESS LIQUID WITH NO ODOR. ------------------------------------------------------------------------------ 4 - FIRE AND EXPLOSION HAZARD DATA ------------------------------------------------------------------------------ FLASH POINT (CLOSED CUP: N/A NFPA 704M RATING: 3-0-0 FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A % FIRE EXTINGUISHING MEDIA USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE. SPECIAL FIRE-FIGHTING PROCEDURES FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE. TOXIC GASES PRODUCED NITROGEN OXIDES, HYDROGEN FLUORIDE, AMMONIA ------------------------------------------------------------------------------ 5 - HEALTH HAZARD DATA ------------------------------------------------------------------------------ TOXICITY TEST RESULTS AND SAFETY AND HEALTH EFFECTS ARE BASED ON THE SOLUTE. THRESHOLD LIMIT VALUE (TLV/TWA): 2.5 MG/M3 ( PPM) PERMISSIBLE EXPOSURE LIMIT (PEL): 2.5 MG/M3 ( PPM) TOXICITY: LD50 (IPR-RAT)(MG/KG) - 32 CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO EFFECTS OF OVEREXPOSURE INHALATION OF VAPORS MAY CAUSE SEVERE IRRITATION OF THE RESPIRATORY SYSTEM. CONTACT WITH SKIN OR EYES MAY CAUSE SEVERE IRRITATION OR BURNS. SKIN ABSORPTION MAY BE HARMFUL. INGESTION MAY CAUSE NAUSEA, VOMITING, GASTROINTESTINAL IRRITATION, AND BURNS TO MOUTH AND THROAT. CHRONIC EFFECTS MAY INCREASE BONE DENSITY, CAUSE CALCIUM DEPOSITS IN LIGAMENTS, AND MOTTLE TOOTH ENAMEL. TARGET ORGANS EYES, SKIN, RESPIRATORY SYSTEM, CENTRAL NERVOUS SYSTEM, KIDNEYS MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE NONE IDENTIFIED ROUTES OF ENTRY INHALATION, INGESTION, EYE CONTACT, SKIN CONTACT ------------------------------------------------------------------------------ MSDS for AMMONIUM FLUORIDE, 40% SOLUTION Page 3 ------------------------------------------------------------------------------ EMERGENCY AND FIRST AID PROCEDURES CALL A PHYSICIAN. IF SWALLOWED, DO NOT INDUCE VOMITING; IF CONSCIOUS, GIVE WATER, MILK, OR MILK OF MAGNESIA. IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. IF SKIN BECOMES IRRITATED, IMMERSE AND SOAK THE AFFECTED AREA, FOR AT LEAST 30 MINUTES, IN ONE OF THE FOLLOWING: ICED 0.13% AQUEOUS ZEPHIRAN CHLORIDE SOLUTION, ICED 70% ALCOHOL SOLUTION, OR ICE-COLD SATURATED SOLUTION OF MAGNESIUM SULFATE. NOTE: DO NOT USE ZEPHIRAN CHLORIDE SOLUTION ON EYES. ------------------------------------------------------------------------------ 6 - REACTIVITY DATA ------------------------------------------------------------------------------ STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR CONDITIONS TO AVOID: HEAT INCOMPATIBLES: STRONG OXIDIZING AGENTS, MOST COMMON METALS, STRONG ACIDS, STRONG BASES, GLASS DECOMPOSITION PRODUCTS: HYDROGEN FLUORIDE, AMMONIA, OXIDES OF NITROGEN ------------------------------------------------------------------------------ 7 - SPILL AND DISPOSAL PROCEDURES ------------------------------------------------------------------------------ STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING. STOP LEAK IF YOU CAN DO SO WITHOUT RISK. VENTILATE AREA. CAREFULLY NEUTRALIZE SPILL WITH DILUTE HCL. FLUSH AREA WITH FLOODING AMOUNTS OF WATER. (USE CAUTION.) DISPOSAL PROCEDURE DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL ENVIRONMENTAL REGULATIONS. ------------------------------------------------------------------------------ 8 - PROTECTIVE EQUIPMENT ------------------------------------------------------------------------------ VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV REQUIREMENTS. RESPIRATORY PROTECTION: A RESPIRATOR WITH DUST/MIST FILTER IS RECOMMENDED. IF AIRBORNE CONCENTRATION EXCEEDS TLV, A SELF- CONTAINED BREATHING APPARATUS IS ADVISED. EYE/SKIN PROTECTION: SAFETY GOGGLES AND FACE SHIELD, UNIFORM, PROTECTIVE SUIT, NEOPRENE GLOVES ARE RECOMMENDED. ------------------------------------------------------------------------------ 9 - STORAGE AND HANDLING PRECAUTIONS ------------------------------------------------------------------------------ ------------------------------------------------------------------------------ MSDS for AMMONIUM FLUORIDE, 40% SOLUTION Page 4 ------------------------------------------------------------------------------ SAF-T-DATA(TM) STORAGE COLOR CODE: BLUE (HEALTH) SPECIAL PRECAUTIONS KEEP CONTAINER TIGHTLY CLOSED. STORE IN SECURE POISON AREA. ISOLATE FROM INCOMPATIBLE MATERIALS. ------------------------------------------------------------------------------ 10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION ------------------------------------------------------------------------------ DOMESTIC (D.O.T.) PROPER SHIPPING NAME AMMONIUM FLUORIDE, SOLUTION (AIR ONLY) HAZARD CLASS ORM-B UN/NA UN2505 LABELS NONE REPORTABLE QUANTITY 100 LBS. INTERNATIONAL (I.M.O.) PROPER SHIPPING NAME AMMONIUM FLUORIDE, SOLUTION HAZARD CLASS 6.1 UN/NA UN2505 LABELS HARMFUL - STOW AWAY FROM FOOD STUFFS