------------------------------------------------------------------------------ MSDS for ANILINE Page 1 ------------------------------------------------------------------------------ ------------------------------------------------------------------------------ 1 - PRODUCT IDENTIFICATION ------------------------------------------------------------------------------ PRODUCT NAME: ANILINE FORMULA: C6H5NH2 FORMULA WT: 93.13 CAS NO.: 00062-53-3 NIOSH/RTECS NO.: BW6650000 COMMON SYNONYMS: BENZAMINE; ANILINE OIL, PHENYLAMINE; AMINOBENZENE; BENZENAMINE PRODUCT CODES: 9110,9112 EFFECTIVE: 08/27/86 REVISION #02 PRECAUTIONARY LABELLING BAKER SAF-T-DATA(TM) SYSTEM HEALTH - 3 SEVERE (POISON) FLAMMABILITY - 2 MODERATE REACTIVITY - 2 MODERATE CONTACT - 3 SEVERE (LIFE) HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD). LABORATORY PROTECTIVE EQUIPMENT STOP SIGN - SEE SECTION VIII FOR PRECAUTIONS PRECAUTIONARY LABEL STATEMENTS POISON DANGER COMBUSTIBLE VAPOR EXTREMELY IRRITATING MAY BE FATAL IF SWALLOWED, INHALED, OR ABSORBED THROUGH SKIN EXCEPTIONAL CONTACT HAZARD - READ MATERIAL SAFETY DATA SHEET KEEP AWAY FROM HEAT, SPARKS, FLAME. DO NOT GET IN EYES, ON SKIN, ON CLOTHING. DO NOT BREATHE VAPOR. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. IN CASE OF FIRE, USE WATER SPRAY, ALCOHOL FOAM, DRY CHEMICAL, OR CARBON DIOXIDE. FLUSH SPILL AREA WITH WATER SPRAY. SAF-T-DATA(TM) STORAGE COLOR CODE: RED (FLAMMABLE) ------------------------------------------------------------------------------ 2 - HAZARDOUS COMPONENTS ------------------------------------------------------------------------------ COMPONENT % CAS NO. ANILINE 90-100 62-53-3 ------------------------------------------------------------------------------ 3 - PHYSICAL DATA ------------------------------------------------------------------------------ ------------------------------------------------------------------------------ MSDS for ANILINE Page 2 ------------------------------------------------------------------------------ BOILING POINT: 184 C ( 363 F) VAPOR PRESSURE(MM HG): 0.6 MELTING POINT: -6 C ( 21 F) VAPOR DENSITY(AIR=1): 3.22 SPECIFIC GRAVITY: 1.02 EVAPORATION RATE: <1 (H2O=1) (BUTYL ACETATE=1) SOLUBILITY(H2O): MODERATE (1 TO 10 %) % VOLATILES BY VOLUME: N/A APPEARANCE & ODOR: OILY LIQUID, COLORLESS UNLESS EXPOSED TO AIR OR LIGHT. ------------------------------------------------------------------------------ 4 - FIRE AND EXPLOSION HAZARD DATA ------------------------------------------------------------------------------ FLASH POINT (CLOSED CUP: 70 C ( 158 F) NFPA 704M RATING: 3-2-0 FLAMMABLE LIMITS: UPPER - N/A % LOWER - 1.3 % FIRE EXTINGUISHING MEDIA USE WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL OR ORDINARY FOAM. SPECIAL FIRE-FIGHTING PROCEDURES FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE. MOVE CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK. USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL. UNUSUAL FIRE & EXPLOSION HAZARDS GIVES OFF FLAMMABLE VAPORS. VAPORS MAY FORM EXPLOSIVE MIXTURE WITH AIR. CLOSED CONTAINERS EXPOSED TO HEAT MAY EXPLODE. CONTACT WITH STRONG OXIDIZERS MAY CAUSE FIRE. TOXIC GASES PRODUCED AMMONIA, NITROGEN OXIDES, CARBON MONOXIDE, CARBON DIOXIDE ------------------------------------------------------------------------------ 5 - HEALTH HAZARD DATA ------------------------------------------------------------------------------ TLV AND PEL LISTED DENOTE (SKIN). THRESHOLD LIMIT VALUE (TLV/TWA): 10 MG/M3 ( 2 PPM) PERMISSIBLE EXPOSURE LIMIT (PEL): 19 MG/M3 ( 5 PPM) TOXICITY: LD50 (ORAL-RAT)(MG/KG) - 250 LD50 (SKN-RAT) (MG/KG) - 1400 LD50 (IPR-RAT)(MG/KG) - 420 LC50 (INHL-MOUSE-7H) (PPM) - 175 CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO EFFECTS OF OVEREXPOSURE ACUTE POISONING VIA ALL ROUTES OF EXPOSURE MAY BE SEVERE ENOUGH TO BE ------------------------------------------------------------------------------ MSDS for ANILINE Page 3 ------------------------------------------------------------------------------ FATAL. ANILINE POISONING IS CHARACTERIZED BY METHEMOGLOBIN FORMATION IN THE BLOOD, RESULTING IN CYANOSIS. OTHER SYMPTOMS THAT MAY OCCUR BECAUSE OF INHALATION OF VAPORS, SKIN ABSORPTION, OR INGESTION ARE HEADACHE, NAUSEA, VOMITING, CONFUSION, DIZZINESS, DROWSINESS, AND LOSS OF CONSCIOUSNESS. LIQUID MAY BE IRRITATING TO SKIN AND EYES. LIQUID MAY CAUSE PERMANENT EYE DAMAGE. CHRONIC EFFECTS OF OVEREXPOSURE MAY INCLUDE ANEMIA, ANOREXIA, AND SKIN LESIONS. CHRONIC EFFECTS OF OVEREXPOSURE MAY INCLUDE KIDNEY AND/OR LIVER DAMAGE. TARGET ORGANS BLOOD, CARDIOVASCULAR SYSTEM, LIVER, KIDNEYS MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE NONE IDENTIFIED ROUTES OF ENTRY INHALATION, ABSORPTION, INGESTION, EYE CONTACT, SKIN CONTACT EMERGENCY AND FIRST AID PROCEDURES CALL A PHYSICIAN. IF SWALLOWED, IF CONSCIOUS, IMMEDIATELY INDUCE VOMITING. IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. THOROUGH CLEANSING OF THE ENTIRE CONTAMINATED AREA OF THE BODY INCLUDING SCALP AND NAILS IS OF THE UTMOST IMPORTANCE. ------------------------------------------------------------------------------ 6 - REACTIVITY DATA ------------------------------------------------------------------------------ STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR CONDITIONS TO AVOID: HEAT, FLAME, OTHER SOURCES OF IGNITION, AIR, LIGHT INCOMPATIBLES: STRONG OXIDIZING AGENTS, STRONG BASES, STRONG ACIDS, ALKALIES, ZINC, ALUMINUM, RUBBER, LEATHER, SOLUTIONS CONTAINING IRON SALTS DECOMPOSITION PRODUCTS: OXIDES OF NITROGEN, AMMONIA, CARBON MONOXIDE, CARBON DIOXIDE ------------------------------------------------------------------------------ 7 - SPILL AND DISPOSAL PROCEDURES ------------------------------------------------------------------------------ STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING. SHUT OFF IGNITION SOURCES; NO FLARES, SMOKING OR FLAMES IN AREA. STOP LEAK IF YOU CAN DO SO WITHOUT RISK. USE WATER SPRAY TO REDUCE VAPORS. TAKE UP WITH SAND OR OTHER NON-COMBUSTIBLE ABSORBENT MATERIAL AND PLACE INTO ------------------------------------------------------------------------------ MSDS for ANILINE Page 4 ------------------------------------------------------------------------------ CONTAINER FOR LATER DISPOSAL. FLUSH AREA WITH WATER. J. T. BAKER SOLUSORB(R) SOLVENT ADSORBENT IS RECOMMENDED FOR SPILLS OF THIS PRODUCT. DISPOSAL PROCEDURE DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL ENVIRONMENTAL REGULATIONS. EPA HAZARDOUS WASTE NUMBER: U012 (TOXIC WASTE) ------------------------------------------------------------------------------ 8 - PROTECTIVE EQUIPMENT ------------------------------------------------------------------------------ VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV REQUIREMENTS. RESPIRATORY PROTECTION: RESPIRATORY PROTECTION REQUIRED IF AIRBORNE CONCENTRATION EXCEEDS TLV. AT CONCENTRATIONS UP TO 100 PPM, A CHEMICAL CARTRIDGE RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE IS RECOMMENDED. ABOVE THIS LEVEL, A SELF-CONTAINED BREATHING APPARATUS IS RECOMMENDED. EYE/SKIN PROTECTION: SAFETY GOGGLES AND FACE SHIELD, UNIFORM, PROTECTIVE SUIT, RUBBER GLOVES ARE RECOMMENDED. ------------------------------------------------------------------------------ 9 - STORAGE AND HANDLING PRECAUTIONS ------------------------------------------------------------------------------ SAF-T-DATA(TM) STORAGE COLOR CODE: RED (FLAMMABLE) SPECIAL PRECAUTIONS KEEP CONTAINER TIGHTLY CLOSED. STORE IN A COOL, DRY, WELL-VENTILATED, FLAMMABLE LIQUID STORAGE AREA OR CABINET. KEEP PRODUCT OUT OF LIGHT. ------------------------------------------------------------------------------ 10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION ------------------------------------------------------------------------------ DOMESTIC (D.O.T.) PROPER SHIPPING NAME ANILINE HAZARD CLASS POISON B UN/NA UN1547 LABELS POISON REPORTABLE QUANTITY 5000 LBS. INTERNATIONAL (I.M.O.) PROPER SHIPPING NAME ANILINE HAZARD CLASS 6.1 UN/NA UN1547 LABELS POISON ------------------------------------------------------------------------------ MSDS for ANILINE Page 5 ------------------------------------------------------------------------------