------------------------------------------------------------------------------ MSDS for ETHANOL-D6, ANHYDROUS Page 1 ------------------------------------------------------------------------------ ------------------------------------------------------------------------------ 1 - PRODUCT IDENTIFICATION ------------------------------------------------------------------------------ PRODUCT NAME: ETHANOL-D6, ANHYDROUS FORMULA: CD3CD2OD FORMULA WT: 52.10 CAS NO.: 00064-17-5 NIOSH/RTECS NO.: KQ6300000 COMMON SYNONYMS: DEUTERATED ETHANOL, ANHYDROUS PRODUCT CODES: L166 EFFECTIVE: 08/29/86 REVISION #02 PRECAUTIONARY LABELLING BAKER SAF-T-DATA(TM) SYSTEM HEALTH - 3 SEVERE (POISON) FLAMMABILITY - 3 SEVERE (FLAMMABLE) REACTIVITY - 1 SLIGHT CONTACT - 1 SLIGHT HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD). LABORATORY PROTECTIVE EQUIPMENT GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES; CLASS B EXTINGUISHER PRECAUTIONARY LABEL STATEMENTS POISON DANGER FLAMMABLE MAY BE FATAL IF SWALLOWED KEEP AWAY FROM HEAT, SPARKS, FLAME. DO NOT GET IN EYES, ON SKIN, ON CLOTHING. DO NOT BREATHE VAPOR. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. IN CASE OF FIRE, USE WATER SPRAY, ALCOHOL FOAM, DRY CHEMICAL, OR CARBON DIOXIDE. FLUSH SPILL AREA WITH WATER SPRAY. SAF-T-DATA(TM) STORAGE COLOR CODE: RED (FLAMMABLE) ------------------------------------------------------------------------------ 2 - HAZARDOUS COMPONENTS ------------------------------------------------------------------------------ COMPONENT % CAS NO. ETHYL ALCOHOL 90-100 64-17-5 ------------------------------------------------------------------------------ 3 - PHYSICAL DATA ------------------------------------------------------------------------------ BOILING POINT: 78 C ( 172 F) VAPOR PRESSURE(MM HG): 44 ------------------------------------------------------------------------------ MSDS for ETHANOL-D6, ANHYDROUS Page 2 ------------------------------------------------------------------------------ MELTING POINT: -114 C ( -173 F) VAPOR DENSITY(AIR=1): 1.6 SPECIFIC GRAVITY: 0.79 EVAPORATION RATE: N/A (H2O=1) (BUTYL ACETATE=1) SOLUBILITY(H2O): COMPLETE (IN ALL PROPORTIONS) % VOLATILES BY VOLUME: 100 APPEARANCE & ODOR: CLEAR, COLORLESS LIQUID WITH A PLEASANT ODOR. ------------------------------------------------------------------------------ 4 - FIRE AND EXPLOSION HAZARD DATA ------------------------------------------------------------------------------ FLASH POINT (CLOSED CUP 13 C ( 55 F) NFPA 704M RATING: 0-3-0 FLAMMABLE LIMITS: UPPER - 19 % LOWER - 3.3 % FIRE EXTINGUISHING MEDIA USE WATER SPRAY, ALCOHOL FOAM, DRY CHEMICAL OR CARBON DIOXIDE. SPECIAL FIRE-FIGHTING PROCEDURES FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE. MOVE CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK. USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL. UNUSUAL FIRE & EXPLOSION HAZARDS VAPORS MAY FLOW ALONG SURFACES TO DISTANT IGNITION SOURCES AND FLASH BACK. CLOSED CONTAINERS EXPOSED TO HEAT MAY EXPLODE. CONTACT WITH STRONG OXIDIZERS MAY CAUSE FIRE. TOXIC GASES PRODUCED CARBON MONOXIDE, CARBON DIOXIDE ------------------------------------------------------------------------------ 5 - HEALTH HAZARD DATA ------------------------------------------------------------------------------ TOXICITY TEST RESULTS AND HEALTH EFFECTS ARE BASED ON THE NON-DEUTERATED PRODUCT. THRESHOLD LIMIT VALUE (TLV/TWA): 1900 MG/M3 ( 1000 PPM) TOXICITY: LD50 (ORAL-RAT)(MG/KG) - 7060 LD50 (IPR-RAT)(MG/KG) - 4070 LD50 (ORAL-MOUSE)(MG/KG) - 7800 LD50 (IV-RAT) (MG/KG) - 1440 CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO EFFECTS OF OVEREXPOSURE VAPORS MAY BE IRRITATING TO EYES, NOSE AND THROAT. INHALATION OF VAPORS MAY CAUSE HEADACHE, NAUSEA, VOMITING, DIZZINESS, DROWSINESS, IRRITATION OF RESPIRATORY TRACT, AND LOSS OF CONSCIOUSNESS. CONTACT CAN CAUSE EYE IRRITATION. PROLONGED EXPOSURE MAY CAUSE DERMATITIS. ------------------------------------------------------------------------------ MSDS for ETHANOL-D6, ANHYDROUS Page 3 ------------------------------------------------------------------------------ INGESTION MAY CAUSE NAUSEA, VOMITING, HEADACHES, DIZZINESS, GASTROINTESTINAL IRRITATION. INGESTION MAY CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION. TARGET ORGANS NONE IDENTIFIED MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE NONE IDENTIFIED ROUTES OF ENTRY NONE INDICATED EMERGENCY AND FIRST AID PROCEDURES CALL A PHYSICIAN. IF SWALLOWED, IF CONSCIOUS, IMMEDIATELY INDUCE VOMITING. IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. ------------------------------------------------------------------------------ 6 - REACTIVITY DATA ------------------------------------------------------------------------------ STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR CONDITIONS TO AVOID: HEAT, FLAME, OTHER SOURCES OF IGNITION, SUNLIGHT INCOMPATIBLES: STRONG OXIDIZING AGENTS, ALUMINUM, ALKALI METALS DECOMPOSITION PRODUCTS: CARBON MONOXIDE, CARBON DIOXIDE ------------------------------------------------------------------------------ 7 - SPILL AND DISPOSAL PROCEDURES ------------------------------------------------------------------------------ STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING. SHUT OFF IGNITION SOURCES; NO FLARES, SMOKING OR FLAMES IN AREA. STOP LEAK IF YOU CAN DO SO WITHOUT RISK. USE WATER SPRAY TO REDUCE VAPORS. TAKE UP WITH SAND OR OTHER NON-COMBUSTIBLE ABSORBENT MATERIAL AND PLACE INTO CONTAINER FOR LATER DISPOSAL. FLUSH AREA WITH WATER. J. T. BAKER SOLUSORB(R) SOLVENT ADSORBENT IS RECOMMENDED FOR SPILLS OF THIS PRODUCT. DISPOSAL PROCEDURE DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL ENVIRONMENTAL REGULATIONS. EPA HAZARDOUS WASTE NUMBER: D001 (IGNITABLE WASTE) ------------------------------------------------------------------------------ 8 - PROTECTIVE EQUIPMENT ------------------------------------------------------------------------------ ------------------------------------------------------------------------------ MSDS for ETHANOL-D6, ANHYDROUS Page 4 ------------------------------------------------------------------------------ VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV REQUIREMENTS. RESPIRATORY PROTECTION: A CHEMICAL CARTRIDGE RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE IS RECOMMENDED. IF AIRBORNE CONCENTRATION EXCEEDS TLV, A SELF-CONTAINED BREATHING APPARATUS IS ADVISED. EYE/SKIN PROTECTION: SAFETY GOGGLES AND FACE SHIELD, UNIFORM, PROTECTIVE SUIT, RUBBER GLOVES ARE RECOMMENDED. ------------------------------------------------------------------------------ 9 - STORAGE AND HANDLING PRECAUTIONS ------------------------------------------------------------------------------ SAF-T-DATA(TM) STORAGE COLOR CODE: RED (FLAMMABLE) SPECIAL PRECAUTIONS BOND AND GROUND CONTAINERS WHEN TRANSFERRING LIQUID. KEEP CONTAINER TIGHTLY CLOSED. STORE IN A COOL, DRY, WELL-VENTILATED, FLAMMABLE LIQUID STORAGE AREA. ------------------------------------------------------------------------------ 10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION ------------------------------------------------------------------------------ DOMESTIC (D.O.T.) PROPER SHIPPING NAME ETHYL ALCOHOL HAZARD CLASS FLAMMABLE LIQUID UN/NA UN1170 LABELS FLAMMABLE LIQUID INTERNATIONAL (I.M.O.) PROPER SHIPPING NAME ETHANOL HAZARD CLASS 3.2 UN/NA UN1170 LABELS FLAMMABLE LIQUID