------------------------------------------------------------------------------ MSDS for HYDROBROMIC ACID (30-32% IN ACETIC ACID) Page 1 ------------------------------------------------------------------------------ ------------------------------------------------------------------------------ 1 - PRODUCT IDENTIFICATION ------------------------------------------------------------------------------ PRODUCT NAME: HYDROBROMIC ACID (30-32% IN ACETIC ACID) FORMULA: HBR FORMULA WT: 80.92 CAS NO.: 10035-10-6 NIOSH/RTECS NO.: MW3850000 COMMON SYNONYMS: HYDROGEN BROMIDE PRODUCT CODES: N419 EFFECTIVE: 09/05/86 REVISION #02 PRECAUTIONARY LABELLING BAKER SAF-T-DATA(TM) SYSTEM HEALTH - 3 SEVERE (POISON) FLAMMABILITY - 2 MODERATE REACTIVITY - 2 MODERATE CONTACT - 4 EXTREME (CORROSIVE) HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD). LABORATORY PROTECTIVE EQUIPMENT GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES PRECAUTIONARY LABEL STATEMENTS POISON DANGER COMBUSTIBLE CAUSES BURNS HARMFUL IF SWALLOWED OR INHALED DO NOT GET IN EYES, ON SKIN, ON CLOTHING. DO NOT BREATHE VAPOR. KEEP IN TIGHTLY CLOSED CONTAINER IN A COOL AREA. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. IN CASE OF SPILL, FLUSH AWAY BY FLOODING WITH WATER APPLIED QUICKLY TO ENTIRE SPILL. NEUTRALIZE WASHINGS WITH LIME OR SODA ASH. SAF-T-DATA(TM) STORAGE COLOR CODE: WHITE (CORROSIVE) ------------------------------------------------------------------------------ 2 - HAZARDOUS COMPONENTS ------------------------------------------------------------------------------ COMPONENT % CAS NO. HYDROBROMIC ACID 30-32 10035-10-6 ACETIC ACID 68-70 64-19-7 ------------------------------------------------------------------------------ 3 - PHYSICAL DATA ------------------------------------------------------------------------------ BOILING POINT: N/A VAPOR PRESSURE(MM HG): N/A ------------------------------------------------------------------------------ MSDS for HYDROBROMIC ACID (30-32% IN ACETIC ACID) Page 2 ------------------------------------------------------------------------------ MELTING POINT: N/A VAPOR DENSITY(AIR=1): N/A SPECIFIC GRAVITY: 1.31 EVAPORATION RATE: N/A (H2O=1) (BUTYL ACETATE=1) SOLUBILITY(H2O): COMPLETE (IN ALL PROPORTIONS) % VOLATILES BY VOLUME: 100 APPEARANCE & ODOR: COLORLESS OR FAINTLY YELLOW LIQUID WITH SHARP ODOR. ------------------------------------------------------------------------------ 4 - FIRE AND EXPLOSION HAZARD DATA ------------------------------------------------------------------------------ FLASH POINT (CLOSED CUP 39 C ( 103 F) FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A % FIRE EXTINGUISHING MEDIA USE WATER SPRAY, ALCOHOL FOAM, DRY CHEMICAL OR CARBON DIOXIDE. SPECIAL FIRE-FIGHTING PROCEDURES FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE. MOVE EXPOSED CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK. USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL; DO NOT GET WATER INSIDE CONTAINERS. UNUSUAL FIRE & EXPLOSION HAZARDS REACTS WITH MOST METALS TO PRODUCE HYDROGEN GAS, WHICH CAN FORM AN EXPLOSIVE MIXTURE WITH AIR. FLASHPOINT GIVEN IS FOR SOLVENT. TOXIC GASES PRODUCED HYDROGEN BROMIDE ------------------------------------------------------------------------------ 5 - HEALTH HAZARD DATA ------------------------------------------------------------------------------ THRESHOLD LIMIT VALUE (TLV/TWA): 10 MG/M3 ( 3 PPM) PERMISSIBLE EXPOSURE LIMIT (PEL): 10 MG/M3 ( 3 PPM) TOXICITY: LC50 (INHL-RAT-1H) (PPM) - 2858 LC50 (INHL-MOUSE-1H) (PPM) - 814 CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO EFFECTS OF OVEREXPOSURE VAPORS MAY BE IRRITATING TO SKIN, EYES, NOSE AND THROAT. INHALATION OF VAPORS MAY CAUSE COUGHING AND DIFFICULT BREATHING. INHALATION OF VAPORS MAY CAUSE PULMONARY EDEMA. CONTACT WITH SKIN OR EYES MAY CAUSE SEVERE IRRITATION OR BURNS. INGESTION MAY CAUSE NAUSEA, VOMITING, GASTROINTESTINAL IRRITATION, AND BURNS TO MOUTH AND THROAT. ------------------------------------------------------------------------------ MSDS for HYDROBROMIC ACID (30-32% IN ACETIC ACID) Page 3 ------------------------------------------------------------------------------ TARGET ORGANS RESPIRATORY SYSTEM, EYES, SKIN MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE NONE IDENTIFIED ROUTES OF ENTRY INGESTION, EYE CONTACT, SKIN CONTACT EMERGENCY AND FIRST AID PROCEDURES CALL A PHYSICIAN. IF SWALLOWED, DO NOT INDUCE VOMITING; IF CONSCIOUS, GIVE WATER, MILK, OR MILK OF MAGNESIA. IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. WASH CLOTHING BEFORE RE-USE. ------------------------------------------------------------------------------ 6 - REACTIVITY DATA ------------------------------------------------------------------------------ STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR CONDITIONS TO AVOID: HEAT, LIGHT, AIR INCOMPATIBLES: STRONG BASES, MOST COMMON METALS, STRONG OXIDIZING AGENTS, AMMONIA, ALKALIES, CAUSTICS, FLUORINE DECOMPOSITION PRODUCTS: HYDROGEN BROMIDE, HYDROGEN ------------------------------------------------------------------------------ 7 - SPILL AND DISPOSAL PROCEDURES ------------------------------------------------------------------------------ STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING. STOP LEAK IF YOU CAN DO SO WITHOUT RISK. VENTILATE AREA. NEUTRALIZE SPILL WITH SODA ASH OR LIME. WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND COVER; REMOVE FROM AREA. FLUSH SPILL AREA WITH WATER. J. T. BAKER NEUTRASORB(R) OR NEUTRASOL(R) "LOW NA+" ACID NEUTRALIZERS ARE RECOMMENDED FOR SPILLS OF THIS PRODUCT. DISPOSAL PROCEDURE DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL ENVIRONMENTAL REGULATIONS. EPA HAZARDOUS WASTE NUMBER: D002 (CORROSIVE WASTE) ------------------------------------------------------------------------------ 8 - PROTECTIVE EQUIPMENT ------------------------------------------------------------------------------ ------------------------------------------------------------------------------ MSDS for HYDROBROMIC ACID (30-32% IN ACETIC ACID) Page 4 ------------------------------------------------------------------------------ VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV REQUIREMENTS. RESPIRATORY PROTECTION: RESPIRATORY PROTECTION REQUIRED IF AIRBORNE CONCENTRATION EXCEEDS TLV. AT CONCENTRATIONS UP TO 50 PPM, A CHEMICAL CARTRIDGE RESPIRATOR WITH ACID CARTRIDGE IS RECOMMENDED. ABOVE THIS LEVEL, A SELF-CONTAINED BREATHING APPARATUS IS ADVISED. EYE/SKIN PROTECTION: SAFETY GOGGLES AND FACE SHIELD, UNIFORM, PROTECTIVE SUIT, ACID-RESISTANT GLOVES ARE RECOMMENDED. ------------------------------------------------------------------------------ 9 - STORAGE AND HANDLING PRECAUTIONS ------------------------------------------------------------------------------ SAF-T-DATA(TM) STORAGE COLOR CODE: WHITE (CORROSIVE) SPECIAL PRECAUTIONS KEEP CONTAINER TIGHTLY CLOSED. STORE IN CORROSION-PROOF AREA. ISOLATE FROM INCOMPATIBLE MATERIALS. ------------------------------------------------------------------------------ 10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION ------------------------------------------------------------------------------ DOMESTIC (D.O.T.) PROPER SHIPPING NAME CORROSIVE LIQUID, N.O.S. (HYDROBROMIC ACID (30-32% IN HAZARD CLASS CORROSIVE MATERIAL (LIQUID) UN/NA UN1760 LABELS CORROSIVE INTERNATIONAL (I.M.O.) PROPER SHIPPING NAME CORROSIVE LIQUIDS, N.O.S. (HYDROBROMIC ACID (30-32% IN HAZARD CLASS 8 UN/NA UN1760 LABELS CORROSIVE