------------------------------------------------------------------------------ MSDS for NITRIC ACID, FUMING, 90% Page 1 ------------------------------------------------------------------------------ ------------------------------------------------------------------------------ 1 - PRODUCT IDENTIFICATION ------------------------------------------------------------------------------ PRODUCT NAME: NITRIC ACID, FUMING, 90% FORMULA: HNO3 FORMULA WT: 63.01 CAS NO.: 7697-37-2 NIOSH/RTECS NO.: QU5900000 COMMON SYNONYMS: FUMING HYDROGEN NITRATE PRODUCT CODES: 9624 EFFECTIVE: 09/10/86 REVISION #02 PRECAUTIONARY LABELLING BAKER SAF-T-DATA(TM) SYSTEM HEALTH - 4 EXTREME (POISON) FLAMMABILITY - 0 NONE REACTIVITY - 3 SEVERE (OXIDIZER) CONTACT - 4 EXTREME (CORROSIVE) HAZARD RATINGS ARE 0 TO 4 (0 = NO HAZARD; 4 = EXTREME HAZARD). LABORATORY PROTECTIVE EQUIPMENT GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES PRECAUTIONARY LABEL STATEMENTS POISON DANGER SPILLAGE MAY CAUSE FIRE OR LIBERATE DANGEROUS GAS HARMFUL IF INHALED AND MAY CAUSE DELAYED LUNG INJURY LIQUID AND VAPOR CAUSE SEVERE BURNS - MAY BE FATAL IF SWALLOWED STRONG OXIDIZER - CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE KEEP FROM CONTACT WITH CLOTHING AND OTHER COMBUSTIBLE MATERIALS. DO NOT STORE NEAR COMBUSTIBLE MATERIALS. DO NOT GET IN EYES, ON SKIN, ON CLOTHING. DO NOT BREATHE VAPOR. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH ADEQUATE VENTILATION. IN CASE OF FIRE, USE WATER SPRAY, ALCOHOL FOAM, DRY CHEMICAL, OR CARBON DIOXIDE. FLUSH SPILL AREA WITH WATERSPRAY. SAF-T-DATA(TM) STORAGE COLOR CODE: YELLOW (REACTIVE) ------------------------------------------------------------------------------ 2 - HAZARDOUS COMPONENTS ------------------------------------------------------------------------------ COMPONENT % CAS NO. NITRIC ACID, FUMING 90 7697-37-2 ------------------------------------------------------------------------------ 3 - PHYSICAL DATA ------------------------------------------------------------------------------ BOILING POINT: 85 C ( 185 F) VAPOR PRESSURE(MM HG): 51 ------------------------------------------------------------------------------ MSDS for NITRIC ACID, FUMING, 90% Page 2 ------------------------------------------------------------------------------ MELTING POINT: -51 C ( -60 F) VAPOR DENSITY(AIR=1): 2.2 SPECIFIC GRAVITY: 1.50 EVAPORATION RATE: >1 (H2O=1) (BUTYL ACETATE=1) SOLUBILITY(H2O): COMPLETE (IN ALL PROPORTIONS) % VOLATILES BY VOLUME: 100 APPEARANCE & ODOR: YELLOW TO BROWN-RED, CLEAR,STRONGLY FUMING LIQUID. ------------------------------------------------------------------------------ 4 - FIRE AND EXPLOSION HAZARD DATA ------------------------------------------------------------------------------ FLASH POINT (CLOSED CUP N/A NFPA 704M RATING: 3-0-0 OXY FLAMMABLE LIMITS: UPPER - N/A % LOWER - N/A % FIRE EXTINGUISHING MEDIA USE WATER SPRAY. SPECIAL FIRE-FIGHTING PROCEDURES FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE. MOVE CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK. USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL. UNUSUAL FIRE & EXPLOSION HAZARDS STRONG OXIDIZER. CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE. TOXIC GASES PRODUCED NITROGEN OXIDES ------------------------------------------------------------------------------ 5 - HEALTH HAZARD DATA ------------------------------------------------------------------------------ THRESHOLD LIMIT VALUE (TLV/TWA): 5 MG/M3 ( 2 PPM) SHORT-TERM EXPOSURE LIMIT (STEL): 10 MG/M3 ( 4 PPM) PERMISSIBLE EXPOSURE LIMIT (PEL): 5 MG/M3 ( 2 PPM) TOXICITY: LC50 (INHL-RAT-4H) (PPM) - 65 LC50 (INHL-MOUSE-4H) (PPM) - 67 CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO OSHA REG: NO EFFECTS OF OVEREXPOSURE INHALATION OF VAPORS MAY CAUSE COUGHING, CHEST PAINS, DIFFICULTY BREATHING, OR UNCONSCIOUSNESS. INHALATION OF VAPORS MAY CAUSE SEVERE IRRITATION OF THE RESPIRATORY SYSTEM. LIQUID MAY CAUSE SEVERE BURNS TO SKIN AND EYES. INHALATION AND INGESTION ARE HARMFUL AND MAY BE FATAL. INGESTION MAY CAUSE SEVERE BURNING OF MOUTH AND STOMACH. ------------------------------------------------------------------------------ MSDS for NITRIC ACID, FUMING, 90% Page 3 ------------------------------------------------------------------------------ TARGET ORGANS EYES, SKIN, RESPIRATORY SYSTEM, TEETH MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE LUNG DISEASE ROUTES OF ENTRY INHALATION, INGESTION, EYE CONTACT, SKIN CONTACT EMERGENCY AND FIRST AID PROCEDURES CALL A PHYSICIAN. IF SWALLOWED, DO NOT INDUCE VOMITING; IF CONSCIOUS, GIVE WATER, MILK, OR MILK OF MAGNESIA. IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. WASH CLOTHING BEFORE RE-USE. ------------------------------------------------------------------------------ 6 - REACTIVITY DATA ------------------------------------------------------------------------------ STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR CONDITIONS TO AVOID: HEAT, LIGHT INCOMPATIBLES: STRONG BASES, COMBUSTIBLE MATERIALS, STRONG REDUCING AGENTS, MOST COMMON METALS, ORGANIC MATERIALS DECOMPOSITION PRODUCTS: OXIDES OF NITROGEN ------------------------------------------------------------------------------ 7 - SPILL AND DISPOSAL PROCEDURES ------------------------------------------------------------------------------ STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING. STOP LEAK IF YOU CAN DO SO WITHOUT RISK. VENTILATE AREA. NEUTRALIZE SPILL WITH SODA ASH OR LIME. WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND COVER; REMOVE FROM AREA. FLUSH SPILL AREA WITH WATER. KEEP COMBUSTIBLES (WOOD, PAPER, OIL, ETC.) AWAY FROM SPILLED MATERIAL. DISPOSAL PROCEDURE DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL ENVIRONMENTAL REGULATIONS. EPA HAZARDOUS WASTE NUMBER: D001, D002 (IGNITABLE, CORROSIVE WASTE) ------------------------------------------------------------------------------ 8 - PROTECTIVE EQUIPMENT ------------------------------------------------------------------------------ VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV REQUIREMENTS. ------------------------------------------------------------------------------ MSDS for NITRIC ACID, FUMING, 90% Page 4 ------------------------------------------------------------------------------ RESPIRATORY PROTECTION: RESPIRATORY PROTECTION REQUIRED IF AIRBORNE CONCENTRATION EXCEEDS TLV. AT CONCENTRATIONS UP TO 100 PPM, A CHEMICAL CARTRIDGE RESPIRATOR WITH ACID CARTRIDGE IS RECOMMENDED. ABOVE THIS LEVEL, A SELF-CONTAINED BREATHING APPARATUS IS ADVISED. EYE/SKIN PROTECTION: SAFETY GOGGLES AND FACE SHIELD, UNIFORM, PROTECTIVE SUIT, ACID-RESISTANT GLOVES ARE RECOMMENDED. ------------------------------------------------------------------------------ 9 - STORAGE AND HANDLING PRECAUTIONS ------------------------------------------------------------------------------ SAF-T-DATA(TM) STORAGE COLOR CODE: YELLOW (REACTIVE) SPECIAL PRECAUTIONS KEEP CONTAINER TIGHTLY CLOSED. STORE SEPARATELY AND AWAY FROM FLAMMABLE AND COMBUSTIBLE MATERIALS. ------------------------------------------------------------------------------ 10 - TRANSPORTATION DATA AND ADDITIONAL INFORMATION ------------------------------------------------------------------------------ DOMESTIC (D.O.T.) PROPER SHIPPING NAME NITRIC ACID, FUMING, "POISON - INHALATION HAZARD" HAZARD CLASS OXIDIZER UN/NA UN2032 LABELS OXIDIZER, POISON REPORTABLE QUANTITY 1000 LBS. INTERNATIONAL (I.M.O.) PROPER SHIPPING NAME NITRIC ACID, RED FUMING HAZARD CLASS 8, 5.1 UN/NA UN2032 LABELS CORROSIVE, OXIDIZING AGENT, POISON